Communication: Vibrational spectroscopy of atmospherically relevant acid cluster anions: bisulfate versus nitrate core structures.
نویسندگان
چکیده
Infrared multiple photon dissociation spectra for the smallest atmospherically relevant anions of sulfuric and nitric acid allow us to characterize structures and distinguish between clusters with a bisulfate or a nitrate core. We find that bisulfate is the main charge carrier for HSO(4)(-)·H(2)SO(4)·HNO(3) but not for NO(3)(-)·H(2)SO(4)·HNO(3). For the mixed dimer anion, we find evidence for the presence of two isomers: HSO(4)(-)·HNO(3) and NO(3)(-)·H(2)SO(4). Density functional calculations accompany the experimental results and provide support for these observations.
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ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 136 24 شماره
صفحات -
تاریخ انتشار 2012